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Figure 13-1 shows a simple example where a host (19216812) is trying to connect to a server (200111) Using SNAT or Masquerading in this case would apply a transformation to the packet so that the source IP address is changed to the NAT s external IP address (100111) From the server s point of view, it is communicating with the NAT device, not the host directly From the host s point of view, it has unobstructed access to the public Internet If there were multiple clients behind the NAT device (say, 19216813 and 19216814), the NAT would transform all of their packets to appear as if they originated from 100111 as well Alas, this raises a small problem The server is going to send some packets back but how is the NAT device going to know who to send what packet to Herein lies the magic: The NAT device maintains an internal list of client connections and associated server connections called flows Thus, in the first example, the NAT is maintaining a record that 19216811:1025 converts to 100111:49001, which is communicating with 200111:80 When 200111:80 sends a packet back to 100111:49001, the NAT device automatically alters the packet so that the destination IP is set to 19216811:1025 and then passes it back to the client on the private network In its simplest form, a NAT device is only tracking flows Each flow is kept open so long as it sees traffic If the NAT does not see traffic on a given flow for some time, the flow is automatically removed These flows have no idea about the content of the connection itself, only that traffic is passing between two endpoints, and it is the job of the NAT to ensure the packets arrive as each endpoint expects Now let s look at the reverse case, as shown in Figure 13-2: A client from the Internet wants to connect to a server on a private network through a NAT Using DNAT in this situation, we can make it the NAT s responsibility to accept packets on behalf of the server, transform the destination IP of the packets, and then deliver them to the server When the server returns packets to the client, the NAT engine must look up the associated flow and change the packet s source IP address so that it reads from the NAT device rather than from the server itself Turning this into the IP addresses shown in Figure 13-2, we see a server on 19216815:80 and a client on 200222:1025 The client connects to the NAT IP address, 100111:80, and the NAT transforms the packet so that the destination IP address is 19216815 When the server sends a packet back, the NAT device does the reverse, so the client thinks that it is talking to 100111 (Note that this particular form of NAT is also referred to as port address translation, or PAT).

The set of r equations resulting from this reduction procedure is a complete set of independent reactions for the N species considered present in the system However, more than one such set is possible, depending on how the reduction procedure is carried out, but all sets number r and are equivalent The reduction procedure also ensures the following relation:

13:

The phase-equilibrium and chemical-reaction-equilibrium equations are the only ones considered in the foregoing treatment as interrelating the phase-rule variables However, in certain situations special constraints may be placed on the system that allow additional equations to be written over and above those considered in the development of Eq (1336) If the number of equations resulting from special constraints is s, then Eq (1336) must be modified to take account of these s additional equations The still more general form of the phase rule that results is:

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Client: 19216812 Default route: 19216811

(1337)

Duhem's theoremfornonreacting systems was developedin Sec 102 It states that for any closed system formed initially from given masses of particular chemical species, the equilibrium state is completely determined (extensive as well as intensive properties) by specification of any two independent variables This theorem gives the difference between the number of independent variables that completely determine the state of the system and the number of independent equations that can be written connecting these variables:

From: 19216812:1025 To: 200111:80 Eth0: 19216811 NAT Eth1: 100111 From: 100111:49001 To: 200111:80

When chemical reactions occur, a new variable ~j is introduced into the material-balance equations for each independent reaction Furthermore, a new equilibrium relation [Eq (138)] can be written for each independent reaction Therefore, when chemical-reaction equilibrium is superimposed on phase equilibrium, r new variables appear and r new equations can be written The difference between the number of variables and number of equations therefore is unchanged, and Duhem's theorem as originally stated holds for reacting systems as well as for nonreacting systems Most chemical-reaction equilibrium problems are so posed that it is Duhem's theorem that makes them determinate The usual problem is to find the composition of a system that reaches equilibrium from an initial state o f j x e d amounts of of reacting species when the two variables T and P are specified

Server: 200111

When the equilibrium state in a reacting system depends on two or more independent chemical reactions, the equilibrium composition can be found by a direct extension of the methods developed for single reactions One first determines a set of independent reactions as discussed in Sec 138 With each independent reaction there is associated a reaction coordinate in accord with the treatment of Sec 131 In addition, a separate equilibrium constant is evaluated for

Server: 19216815 Default route: 19216811

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